Butylmagnesium chloride

Basic information

  • Product Name:Butylmagnesium chloride
  • CasNo.:693-04-9
  • MF:C4H9ClMg
  • MW:116.873

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:-17°C
  • Packing:green-brown to brown solution
  • Throughput:
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Product Details

CasNo: 693-04-9

MF: C4H9ClMg

Appearance: green-brown to brown solution

Factory Supply Hot Sale High Purity Butylmagnesium chloride 693-04-9 with Fast Shipping and Best Price

  • Molecular Formula:C4H9ClMg
  • Molecular Weight:116.873
  • Appearance/Colour:green-brown to brown solution 
  • Melting Point:-17°C 
  • Boiling Point:66 °C 
  • Flash Point:115 °F 
  • PSA:0.00000 
  • Density:0.962 g/mL at 25 °C 
  • LogP:2.44360 

Butylmagnesium chloride(Cas 693-04-9) Usage

Chemical Properties

green-brown to brown solution

Uses

Butylmagnesium chloride (BuMgCl) is a Grignard reagent. It is used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

InChI:InChI=1/C4H9.ClH.Mg/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1/rC4H9Mg.ClH/c1-2-3-4-5;/h2-4H2,1H3;1H/q+1;/p-1

693-04-9 Relevant articles

Disposable cartridge concept for the on-demand synthesis of turbo Grignards, Knochel–Hauser amides, and magnesium alkoxides

Adamo, Andrea,Berton, Mateo,McQuade, D. Tyler,Sheehan, Kevin

supporting information, p. 1343 - 1356 (2020/07/10)

Magnesium organometallic reagents occupy...

The Conjugate Addition of tert-Butylmagnesium Chloride to 3, 6-Disubstituted Pyridazines

I CROSSLAND

, Acta Chemica Scandinavica, 1962

The reaction between the disubstituted pyridazines (I and III) and tertbutylmagnesium chloride is distinctly exothermic and takes place readily at the reflux temperature of ether.

Polylactones: 32. High-molecular-weight polylactides by ring-opening polymerization with dibutylmagnesium or butylmagnesium chloride

Hans R. Kricheldorf, Soo-Ran Lee

, Polymer Volume 36, Issue 15, 1995, Pages 2995-3003

Recently, it was shown that racemisation of L-LA occurred by heating in bulk above 180 °C during 30–60 min [32]. Racemisation increased with time, temperature and in the presence of magnesium oxide, dibutylmagnesium or butylmagnesium chloride as catalyst [30–32].

Association and Dissociation of Grignard Reagents RMgCl and Their Turbo Variant RMgC?LiCl

Schnegelsberg, Christoph,Bachmann, Sebastian,Kolter, Marlene,Auth, Thomas,John, Michael,Stalke, Dietmar,Koszinowski, Konrad

supporting information, p. 7752 - 7762 (2016/06/08)

Grignard reagents RMgCl and their so-cal...

693-04-9 Process route

triethylaluminum
97-93-8

triethylaluminum

n-butyl-ethylmagnesium
62202-86-2

n-butyl-ethylmagnesium

hydridomagnesium chloride
14989-29-8

hydridomagnesium chloride

(AlEt<sub>3</sub>)2*MgEt<sub>2</sub>

(AlEt3)2*MgEt2

butyl magnesium bromide
693-04-9

butyl magnesium bromide

ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

magnesium chloride
7786-30-3

magnesium chloride

Conditions
Conditions Yield
In 2-Methylpentane; for 4383h; Reactivity;
 
butyltriethoxy silane
4781-99-1

butyltriethoxy silane

EtOMgCl

EtOMgCl

tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

butyl magnesium bromide
693-04-9

butyl magnesium bromide

Conditions
Conditions Yield
In tert-butyl methyl ether; toluene; at 20 ℃; Solvent; Equilibrium constant; Inert atmosphere;
 

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